Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 23(11), p. 3776, 2013
DOI: 10.1039/c3ob40388b
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Formation of C=N bonds by the release of H2: A new strategy for synthesis of imines and benzazoles
Journal article published in 2013 by
Xukang Jin,
Yuxiao Liu,
Qiongqiong Lu,
Dejun Yang,
Jiangkai Sun,
Shuangshuang Qin,
Jingwu Zhang,
Jiaxuan Shen,
Changhu Chu,
Renhua Liu
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Abstract
A new strategy for synthesis of imines using the approach of release of H2 has been developed. This oxidant- and acceptor-free Pd/C catalysis protocol is further applied to synthesis of benzoxazoles, benzimidazoles, and benzothiazoles through a one-pot cascade reaction with notably high yields.