Published in
Royal Society of Chemistry, Chemical Communications, 29(49), p. 2992
DOI: 10.1039/c3cc40819a
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Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal–organic framework NU-111
Journal article published in 2013 by
Yang Peng,
Gadipelli Srinivas,
Christopher E. Wilmer,
Ibrahim Eryazici,
Randall Q. Snurr 
,
Joseph T. Hupp,
Taner Yildirim,
Omar K. Farha
,
Joseph T. Hupp,
Taner Yildirim,
Omar K. Farha
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Abstract
We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g-1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.