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Wiley-VCH Verlag, ChemInform, 20(44), p. no-no, 2013

DOI: 10.1002/chin.201320052

Royal Society of Chemistry, Chemical Communications, 7(49), p. 674-676

DOI: 10.1039/c2cc37385h

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Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Novel ruthenium(ii) complexes were obtained as a result of a stoichiometric reaction of Grubbs' benzylidene second generation catalysts with 3-nitropropene. These stable complexes, formally ruthenaisoxazole N-oxide derivatives, display activity in both metathesis and non-metathetic processes such as cycloisomerisation, isomerisation and transfer hydrogenation.