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Royal Society of Chemistry, Chemical Communications, 1(47), p. 221-223

DOI: 10.1039/c002435j

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A triangulopalladium cluster consisting of μ3-capping silyl ligands

Journal article published in 2011 by Felix Armbruster, Jens Meyer, Alexander Baldes, Pascual Oña Burgos, Ignacio Fernández ORCID, Frank Breher
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

We report on the utility of multifunctional, κ(1)Si:κ(3)S-coordinated tris(methimazolyl)silanide ligands [Si(mt(Me))(3)](-) for the stabilisation of a triangulo palladium cluster [Pd(3){Si(mt(Me))(3)}(2)] (3) consisting of very unusual μ(3)-capping SiR(3) donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.