Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

Mihaylov, M.; Chakarova, K.; Andonova, S.; Drenchev, N.; Ivanova, E.; Pidko, E. A.; Sabetghadam, A.; Seoane, B.; Gascon, J.; Kapteijn, F.; Hadjiivanov, K.

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Royal Society of Chemistry, Chemical Communications, 7(52), p. 1494-1497, 2016

DOI: 10.1039/c5cc08677a

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Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

Journal article published in 2016 by M. Mihaylov, K. Chakarova, S. Andonova, N. Drenchev, E. Ivanova, E. A. Pidko

, A. Sabetghadam, B. Seoane, J. Gascon, F. Kapteijn, K. Hadjiivanov

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Abstract

FTIR spectra of ¹²CO₂ and ¹²CO₂ + ¹³CO₂ mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO₂)₂ species connected to two structural OH groups.

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Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

Abstract