Published in
Royal Society of Chemistry, Journal of the Chemical Society. Perkin transactions 1, 6, p. 1535-1540, 1990
DOI: 10.1039/p19900001535
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Partial syntheses of some isomers of Gibberellin A1 and Gibberellin A3 methyl ester
Journal article published in 1990 by
Braulio M. Fraga,
Emilio de Paz,
C. D. Górnez,
Clemente D. G�mez,
M. G. Hernández,
Melchor G. Hern�ndez,
E. De Paz,
Fernando G. Tellado 
,
Aurea A. Perales
,
Aurea A. Perales
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Abstract
The partial synthesis of an isomer of gibberellic acid methyl ester, with a lactone between C-6 and C-10 and an esterified acid group at C-19, is described. The overall yield from gibberellic acid was 46%. The preparation of 6-epi-GA1 has also been carried out. Its structure was confirmed by an X-ray analysis of its 1 β-iodo derivative.