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Royal Society of Chemistry, Chemical Communications, 1(47), p. 388-390, 2011

DOI: 10.1039/c0cc02164d

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Synthesis and characterization of an infinite sheet of metal-alkyl bonds: Unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Journal article published in 2011 by Sharon E. Baillie, William Clegg ORCID, Pablo García-Álvarez, Eva Hevia ORCID, Alan R. Kennedy, Jan Klett, Luca Russo
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The study of co-complexation reactions between NaCH(2)SiMe(3) and Mg(CH(2)SiMe(3))(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH(2)SiMe(3))(3)}(∞)] (1) as well as the related solvent-free sodium alkyl [{(NaCH(2)SiMe(3))(4)}(∞)] (3).