A novel two-dimensional mixed molybdenum–vanadium polyoxometalate with two types of cobalt(ii) complex fragments as bridgesElectronic supplementary information (ESI) available: synthesis and characterization of 1. Fig. S1: view of layers down the a axis of 1. Fig. S2: plots of χT and χ–1 vs. T for 1. See http://www.rsc.org/suppdata/cc/b2/b202540j/

Liu, Cai-Ming; Zhang, De-Qing; Xiong, Ming; Zhu, Dao-Ben

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Royal Society of Chemistry, Chemical Communications, 13, p. 1416-1417

DOI: 10.1039/b202540j

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A novel two-dimensional mixed molybdenum–vanadium polyoxometalate with two types of cobalt(ii) complex fragments as bridgesElectronic supplementary information (ESI) available: synthesis and characterization of 1. Fig. S1: view of layers down the a axis of 1. Fig. S2: plots of χT and χ–1 vs. T for 1. See http://www.rsc.org/suppdata/cc/b2/b202540j/

Journal article published in 2002 by Cai-Ming Liu

, De-Qing Zhang, Ming Xiong, Dao-Ben Zhu

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Abstract

A heterometallic polyoxometalate [Co(en)2][Co(bpy)2]2[PMoVI5MoV3VIV8O44]·4.5H2O (en = ethylenediamine, bpy = 2,2′-bipyridine) 1, has been hydrothermally synthesized, which is the first example of a two-dimensional framework where polyoxometalate anions are linked by two types of complex fragments.

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