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Royal Society of Chemistry, Nanoscale, 16(4), p. 5138, 2012

DOI: 10.1039/c2nr30986f

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Strongly exchange coupled inverse ferrimagnetic soft/hard, MnxFe3-xO4/FexMn3-xO4, core/shell heterostructured nanoparticles

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Inverted soft/hard, in contrast to conventional hard/soft, bi-magnetic core/shell nanoparticles of Mn(x)Fe(3-x)O(4)/Fe(x)Mn(3-x)O(4) with two different core sizes (7.5 and 11.5 nm) and fixed shell thickness (∼0.6 nm) have been synthesized. The structural characterization suggests that the particles have an interface with a graded composition. The magnetic characterization confirms the inverted soft/hard structure and evidences a strong exchange coupling between the core and the shell. Moreover, larger soft core sizes exhibit smaller coercivities and loop shifts, but larger blocking temperatures, as expected from spring-magnet or graded anisotropy structures. The results indicate that, similar to thin film systems, the magnetic properties of soft/hard core/shell nanoparticles can be fine tuned to match specific applications.