Royal Society of Chemistry, Chemical Communications, 6(50), p. 679-681, 2014
DOI: 10.1039/c3cc47868h
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Incorporating biphenyls as co-monomers in electron-deficient diketopyrrolopyrrole (DPP) conjugated polymers enables widening the optical band gap to 1.70 eV. Power conversion efficiencies of 3.7-5.7% and high open-circuit voltages of 0.80-0.93 V are obtained in solar cells based on these wide band gap DPP polymers.