Published in
Royal Society of Chemistry, Dalton Transactions, 42(44), p. 18324-18328, 2015
DOI: 10.1039/c5dt03320a
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A High-Pressure Crystallographic and Magnetic Study of Na5[Mn(L-tart)2]•12H2O (L-tart = L-tartrate)
Journal article published in 2015 by
Gavin A. Craig 
,
Christopher H. Woodall,
Scott Campbell McKellar,
Michael R. Probert,
Konstantin V. Kamenev,
Stephen A. Moggach,
Euan K. Brechin ,
Simon Parsons,
Mark Murrie
,
Christopher H. Woodall,
Scott Campbell McKellar,
Michael R. Probert,
Konstantin V. Kamenev,
Stephen A. Moggach,
Euan K. Brechin ,
Simon Parsons,
Mark Murrie
This paper is made freely available by the publisher.
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Abstract
The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na(+) ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.