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Royal Society of Chemistry, Dalton Transactions, 6(45), p. 2390-2393

DOI: 10.1039/c5dt04528b

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White phosphorus activation by a Th(III) complex

Journal article published in 2016 by Alasdair Formanuik, Fabrizio Ortu, Reece Beekmeyer, Andrew Kerridge ORCID, Ralph W. Adams ORCID, David P. Mills ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

[Th(Cp′′)3] (Cp′′ = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp′′)3}2(μ-η1:η1-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.