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Wiley-VCH Verlag, ChemInform, 35(40), 2009

DOI: 10.1002/chin.200935100

Royal Society of Chemistry, Chemical Communications, 17, p. 2368

DOI: 10.1039/b819613c

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Ambiphilic allenes: Synthesis and reactivity

Journal article published in 2009 by David Tejedor ORCID, Gabriela Méndez-Abt, Javier González-Platas ORCID, Miguel A. Ramírez, Fernando García-Tellado ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Ambiphilic allenes are generated by an organocatalyzed domino reaction of alkyl propiolates and aromatic 1,2-diketones; in the absence of any external chemical agent, these allenes perform a thermally-driven dimerization reaction to generate the corresponding fully-substituted cyclobutanes in a regio- and highly stereoselective manner.