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Royal Society of Chemistry, Journal of the Chemical Society, Chemical Communications, 16, p. 1839

DOI: 10.1039/c39940001839

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Heterometallic Carbonyl Cluster Oxide. Formation, Structure and Reactivity of WRe2 Oxo-Acetylide Cluster Compounds

Journal article published in 1994 by Hsiao-Ling Wu, Puu-Shum Cheng, Der-Kweng Hwang, Pei-Chiun Su, Y.;Cheng P.;Wu H.;Hwang D.;Su P.;彭旭明;Lee G Chi, Shie-Ming Peng, Y.;Cheng P.;Wu H.;Hwang D.;Su P.;Peng Shie-Ming;Lee G Chi ORCID, Gene-Hsiang Lee, Y;Cheng Ps;Wu Hl;Kwang Dk;Su Pc;Peng Sm;Lee Gh Chi
This paper is available in a repository.
This paper is available in a repository.

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Abstract

2010302010075 ; 化學系 ; Cluster [WRe2(C(5)Me(5))(O)(CO)(8)(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe2(C(5)Me(5))(CO)(9)(CCPh)] with O-2 or N2O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.