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Royal Society of Chemistry, Chemical Communications, 15, p. 1545-1546

DOI: 10.1039/a803434f

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Dynamic cis/trans isomerisation in a porphyrin–fullerene conjugate

Journal article published in 1998 by Jean-François Nierengarten ORCID, Jean-François Nicoud
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A porphyrin with two fullerene substituents is prepared by condensation of a C60 aldehyde derivative and dipyrrol-2-yl methane and by reaction of a preconstructed porphyrin with C60 itself; it is obtained as a mixture of two conformers in slow equilibrium, as shown by a variable temperature NMR study.