Wiley-VCH Verlag, ChemInform, 28(46), p. no-no, 2015
Royal Society of Chemistry, Chemical Communications, 18(51), p. 3778-3781
DOI: 10.1039/c4cc09850a
Full text: Unavailable
This work describes the design and application of a single-pot, reductive arene C–H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.