Published in
Royal Society of Chemistry, Chemical Communications, 71(48), p. 8952, 2012
DOI: 10.1039/c2cc33929c
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Conducting metallophthalocyanine 2D covalent organic frameworks: The role of central metals in controlling π-electronic functions
Journal article published in 2012 by
Xuesong Ding,
Xiao Feng,
Akinori Saeki,
Shu Seki,
Atsushi Nagai 
,
Donglin Jiang
,
Donglin Jiang
This paper is available in a repository.
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Abstract
Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine π-columns. The central metals control the π-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.