Royal Society of Chemistry, Chemical Communications, 99(50), p. 15807-15810
DOI: 10.1039/c4cc08214a
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A rare (3,4,5)-connected self-interpenetrated metal-organic framework with O-atom lined pore surface has been constructed from Zn(II) and H4L (H4L = 5,5'-(1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7(1H,3H,6H,8H)diyl)-diisophthalic acid), which features an unprecedented 1D + 2D → 3D self-interpenetrated array and shows good property in drug controlled release.