Published in
Royal Society of Chemistry, Dalton Transactions, 28(43), p. 10690-10694, 2014
DOI: 10.1039/c4dt01469c
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A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks
Journal article published in 2014 by
J. M. Frost,
S. Sanz,
T. Rajeshkumar,
M. B. Pitak,
S. J. Coles 
,
G. Rajaraman,
W. Wernsdorfer,
J. Schnack,
P. J. Lusby,
E. K. Brechin
,
G. Rajaraman,
W. Wernsdorfer,
J. Schnack,
P. J. Lusby,
E. K. Brechin
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Abstract
The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [MnIII12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.