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Royal Society of Chemistry, Chemical Communications, 11(51), p. 2044-2047, 2015

DOI: 10.1039/c4cc08811e

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The first 4d/4f single molecule magnet containing a {RuIII2DyIII2} core

Journal article published in 2014 by Stuart K. Langley, Daniel P. Wielechowski, Veacheslav Vieru, Nicholas F. Chilton ORCID, Boujemaa Moubaraki, Liviu F. Chibotaru ORCID, Keith S. Murray
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This paper is available in a repository.

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Abstract

We report the synthesis, structure and magnetic properties of the first 4d-4f single molecule magnet. The complex [RuIII2DyIII2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm-1. Ab initio and DFT calculations provide insight into the observed magnetic behaviour.