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Royal Society of Chemistry, Dalton Transactions, 14(45), p. 6004-6014, 2016

DOI: 10.1039/c5dt02535d

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Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes

Journal article published in 2015 by Conrad A. P. Goodwin, Inigo Vitorica Yrezabal, Alex Smith, Fabrizio Ortu, Iñigo J. Vitorica-Yrezabal ORCID, David P. Mills ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The effectiveness of simple synthetic routes to access silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes from commercially available Grignard reagents is explored herein.