Published in
Royal Society of Chemistry, Chemical Communications, 44, p. 5845
DOI: 10.1039/b811357b
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Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex
Journal article published in 2008 by
Mark E. Smith,
Emma L. Flynn,
Mark A. Fox 
,
Alexandre Trottier,
Eckart Wrede,
Dmitri S. Yufit,
Judith A. K. Howard,
Kate L. Ronayne,
Michael Towrie ,
Anthony W. Parker,
Frantisek Hartl,
Paul J. Low
,
Alexandre Trottier,
Eckart Wrede,
Dmitri S. Yufit,
Judith A. K. Howard,
Kate L. Ronayne,
Michael Towrie ,
Anthony W. Parker,
Frantisek Hartl,
Paul J. Low
This paper is available in a repository.
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Abstract
Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}(mu-C[triple bond]CC[triple bond]N){Re(CO)(3)(bpy)}]PF(6) has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.