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Royal Society of Chemistry, CrystEngComm, 35(16), p. 8098-8101

DOI: 10.1039/c4ce00729h

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Assembly of a calix[4]arene-supported MnIIIMnIIcluster mediated by halogen interactions

Journal article published in 2014 by Stephanie M. Taylor, Jamie M. Frost, Ross McLellan, Ruaraidh D. McIntosh, Euan K. Brechin ORCID, Scott J. Dalgarno
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A new calix[4]arene-supported MnIIIMnII cluster, formed by the introduction of 3,5-dichlorobenzoate to a system known to afford MnIII2MnII2 Single-Molecule Magnets (SMMs), assembles in a layered manner through halogen interactions; structural and magnetic properties of this new cluster are presented.