Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 42(3), p. 20992-20998, 2015
DOI: 10.1039/c5ta05111h
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We report a one-pot synthesis of hybrid nanocomposites of Cu-doped Pd-Fe3O4via controlled thermal decomposition of Fe(CO)5 and reduction of Pd(OAc)2 and Cu(acac)2. Sodium oleate, used as a capping agent, affected both the morphologies and surface areas of the Cu-doped Pd-Fe3O4 nanocomposites. To the best of our knowledge, these magnetically recyclable hybrid nanocomposites are a new class of nanocatalysts, and the tandem synthesis of 2-phenylbenzofuran from 2-iodophenol with phenylpropiolic acid catalyzed by heterogeneous nanocatalysts has not been reported in the literature. Moreover, Cu-doped Pd-Fe3O4 nanocatalysts are superior to previously reported catalysts for this tandem reaction.