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Royal Society of Chemistry, Chemical Communications, 66(51), p. 13094-13097, 2015

DOI: 10.1039/c5cc04217h

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Mononuclear Nonheme Iron(IV)-Oxo and Manganese(IV)-Oxo Complexes in Oxidation Reactions: Experimental Results Prove Theoretical Prediction

Journal article published in 2015 by Junying Chen, Kyung Bin Cho, Kyung-Bin Cho ORCID, Yong-Min Lee, Yoon Hye Kwon, Wonwoo Nam ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [M(IV)O(N4Py)](2+) (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and experimental results show that Fe(IV)O is more reactive than Mn(IV)O. The latter is shown to react through excited state reactivity (ESR).