Published in
Royal Society of Chemistry, Dalton Transactions, 22(42), p. 7842, 2013
DOI: 10.1039/c3dt50750e
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Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size
Journal article published in 2013 by
Seungwoo Hong,
Hee So,
Heejung Yoon,
Kyung Bin Cho 
,
Yong-Min Lee,
Shunichi Fukuzumi,
Wonwoo Nam
,
Yong-Min Lee,
Shunichi Fukuzumi,
Wonwoo Nam
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Abstract
The ring size effect of macrocyclic TMC ligands in nonheme iron(iv)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(iv)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe(IV/III) redox potential.