Published in
Royal Society of Chemistry, Chemical Communications, 23(51), p. 4778-4781, 2015
DOI: 10.1039/c4cc10375k
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A simple access to transition metal cyclopropenylidene complexes
Journal article published in 2015 by
Yannick D. Bidal,
Mathieu Lesieur,
Mohand Melaimi,
David B. Cordes,
Alexandra M. Z. Slawin,
Guy Bertrand,
Catherine S. J. Cazin 
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Abstract
We report the first example of BAC-Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au-, Pd-, Ir- and Rh-BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.