Published in
Royal Society of Chemistry, Chemical Communications, 7, p. 744
DOI: 10.1039/b512430a
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A paramagnetic Cu(I)/Cu(II)/Zn(II) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization
Journal article published in 2006 by
Liang Ouyang,
Pedro M. Aguiar 
,
Raymond J. Batchelor,
Scott Kroeker,
Daniel B. Leznoff
,
Raymond J. Batchelor,
Scott Kroeker,
Daniel B. Leznoff
This paper is available in a repository.
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Abstract
A Cu(I)/Cu(II)/Zn(II) mixed-valent [Cu(en)2][Zn(NC)4(CuCN)2] polymer, which has a 2-D layer structure with six structurally inequivalent cyanides in four distinct bonding modes, has been prepared; structurally informative 13C and 15N MAS NMR spectra of this paramagnetic system are readily observable.