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Royal Society of Chemistry, Chemical Communications, 93(50), p. 14504-14507

DOI: 10.1039/c4cc06696k

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New magnetic frameworks of [(CuF<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>)<sub>x</sub>(pyz)]

Journal article published in 2014 by A. Lanza ORCID, C. Fiolka, M. Fisch, N. Casati, M. Skoulatos, C. Rüegg, K. W. Krämer, Piero Macchi ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Other ; Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2- (pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers.