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Royal Society of Chemistry, CrystEngComm, 33(15), p. 6602, 2013

DOI: 10.1039/c3ce41224e

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A structurally versatile coordination polymer: Demonstrating spontaneous resolution, conformational polymorphism and gel formation

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Abstract

Conformationally flexible C2-symmetric 2-(2′-cyanophenoxy) benzonitrile (O,O-CPBN) was self-assembled using silver ions into spontaneously resolved, helical and coordination polymer gel structures including unprecedented four different ligand conformation in a single polymer network structure.