Published in
Royal Society of Chemistry, Chemical Communications, 18(51), p. 3754-3757
DOI: 10.1039/c5cc00453e
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Enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes
Journal article published in 2015 by
Nidal M. Saleh,
Monika Srebro 
,
Thibault Reynaldo,
Nicolas Vanthuyne,
Loïc Toupet,
Victoria Y. Chang,
Gilles Muller,
J. A. Gareth Williams,
J. A. Gareth Williams,
Christian Roussel,
Jochen Autschbach ,
Jeanne Crassous
,
Thibault Reynaldo,
Nicolas Vanthuyne,
Loïc Toupet,
Victoria Y. Chang,
Gilles Muller,
J. A. Gareth Williams,
J. A. Gareth Williams,
Christian Roussel,
Jochen Autschbach ,
Jeanne Crassous
This paper is made freely available by the publisher.
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Abstract
The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.