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Royal Society of Chemistry, Chemical Communications, 1(49), p. 48-50

DOI: 10.1039/c2cc37442k

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Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

Journal article published in 2012 by Mengtao Ma ORCID, Mengtao, Anastas Sidiropoulos, Lalrempuia Ralte, Andreas Stasch ORCID, Cameron Jones
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Reactions of [Pt(PCy(3))(2)] (Cy = cyclohexyl) with group 12 metal dihalides have afforded the novel metal only Lewis pair (MOLP) complexes, [(Cy(3)P)(2)Pt→MX(2)] (M = Zn or Cd, X = Br or I), or the oxidative addition product, trans-[(Cy(3)P)(2)(I)PtHgI]. The zinc complex represents the first MOLP to contain an unsupported Pt→Zn linkage.