Published in
Royal Society of Chemistry, Dalton Transactions, 25(42), p. 9033, 2013
DOI: 10.1039/c3dt50131k
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Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts
Journal article published in 2013 by
Stephen M. Mansell 
,
Fanny Bonnet,
Marc Visseaux,
Polly L. Arnold
,
Fanny Bonnet,
Marc Visseaux,
Polly L. Arnold
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Abstract
The synthesis and structural characterisation of the uranium(iv) amido-borohydrides (N'')2U{κ(2)-N(SiMe3)SiMe2CH2BBN-H} and U{κ(2)-N(SiMe3)SiMe2CH2BBN-H}2, and their activity as pre-catalysts for the polymerisation of isoprene are described.