Published in

Royal Society of Chemistry, Chemical Communications, 2(46), p. 315-317, 2010

DOI: 10.1039/b918660c

Links

Tools

Export citation

Search in Google Scholar

Rhodium-mediated activation of an alkane-type C–H bond

Journal article published in 2010 by Anneke Krüger, Antonia Neels, Martin Albrecht ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

Abnormal C4-bonding of N-heterocyclic carbenes effectively modulates the electron density at rhodium and allows for the selective cleavage of an unactivated C(sp(3))-H bond, whereas no such intramolecular C-H bond breaking is observed when the carbene binds normally through the C2 carbon.