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Royal Society of Chemistry, Chemical Communications, 3(50), p. 286-288

DOI: 10.1039/c3cc46922k

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CO2fixation employing an iridium(i)-hydroxide complex

Journal article published in 2014 by Byron J. Truscott, David J. Nelson ORCID, Alexandra M. Z. Slawin ORCID, Steven P. Nolan ORCID
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This paper is available in a repository.

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Abstract

The reactivity of a number of Ir(I) complexes towards CO2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir-O and Ir-N bonds proved facile, yielding a number of Ir(I)-carbonates and -carbamates. Most importantly, reaction between CO2 and Ir(I)-OH led to isolation of the novel [{Ir(I)}2-(μ-κ(1):κ(2)-CO3)] complex.