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Royal Society of Chemistry, Chemical Communications, 3, p. 341-343

DOI: 10.1039/b512312g

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Synthesis and magnetic properties of a 4-(2 '-pyrimidyl)-1,2,3,5-dithiadiazolyl dimanganese complex

Journal article published in 2006 by Michael Jennings, Kathryn E. Preuss ORCID, Jian Wu
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A spin-bearing bis-bidentate ligand, designed from a pyrimidyl-substituted R-CN2S2 neutral radical, is used to co-ordinate two Mn(II) metal centres yielding a thermally stable complex with antiferromagnetic coupling between the ligand-centred spin and the metal-centred spins, and thus an overall ferrimagnetic coupling scheme with a ground state S = 9/2.