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Royal Society of Chemistry, Chemical Communications, 59(50), p. 8010

DOI: 10.1039/c4cc03650f

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Nickel-catalysed carboxylation of organoboronates

Journal article published in 2014 by Yusuke Makida, Enrico Marelli, Alexandra M. Z. Slawin ORCID, Steven P. Nolan ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.