Published in
Royal Society of Chemistry, Chemical Communications, 26(51), p. 5668-5671
DOI: 10.1039/c5cc00500k
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Formation of N3– during interaction of NO with reduced ceria
Journal article published in 2015 by
Mihail Y. Mihaylov,
Elena Z. Ivanova,
Hristiyan A. Aleksandrov 
,
Petko St Petkov,
Georgi N. Vayssilov,
Konstantin I. Hadjiivanov
,
Petko St Petkov,
Georgi N. Vayssilov,
Konstantin I. Hadjiivanov
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Abstract
We show that the first stages of interaction between NO and reduced ceria comprise the formation of azides, N3-, with simultaneous oxidation of Ce3+ to Ce4+. This finding impose revision of some current views of catalytic NO conversion and may contribute to design new deNOx materials and processes.