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Royal Society of Chemistry, Chemical Communications, 25(51), p. 5402-5405

DOI: 10.1039/c4cc08718f

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Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

Journal article published in 2014 by Sean D. Woodall, Adam N. Swinburne, Nidhu lal Banik, Nidhu lal Banik, Andrew Kerridge ORCID, Poppy Di Pietro, Christian Adam, Peter Kaden ORCID, Louise S. Natrajan
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Room temperature detection of neptunyl(vi) LMCT emission in a coordination compound and in the presence of uranyl(vi) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(vi) or uranyl(vi) emission is observed or a sum of the two.