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Royal Society of Chemistry, Chemical Communications, 15(51), p. 3069-3072, 2015

DOI: 10.1039/c4cc09008j

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Single Molecule Level Plasmonic Catalysis – A Dilution Study of p-Nitrothiophenol on Gold Dimers

Journal article published in 2015 by Zhenglong Zhang, Tanja Deckert-Gaudig ORCID, Pushkar Singh, Volker Klaus Deckert ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Surface plasmons on isolated gold dimers can initiate intermolecular reactions of adsorbed p-nitrothiophenol. At the single molecule level when dimerization is not possible an intramolecular reaction can be observed. Experimental evidence indicates that plasmon-induced hot electrons provide the required activation energy.