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Royal Society of Chemistry, Chemical Communications, 23, p. 2460-2461

DOI: 10.1039/b108352j

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Epoxidation of allylic alcohols in aqueous solutions of non surfactant amphiphilic sugars

This paper is available in a repository.
This paper is available in a repository.

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Abstract

A variety of cyclic and acyclic allylic alcohols undergo efficient chemo-, regio- and/or stereoselective epoxidations in neutral aqueous solutions of amphiphilic carbohydrates (sucrose, L-arabinose, methyl or ethyl beta-D-fructopyranoside) by using dilute hydrogen peroxide in the presence of molybdic or tungstic salts.