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Royal Society of Chemistry, Chemical Communications, 3, p. 391-393, 2005

DOI: 10.1039/b414233k

Wiley-VCH Verlag, ChemInform, 22(36), 2005

DOI: 10.1002/chin.200522036

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Rh(ii) catalysed intramolecular C–H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

Journal article published in 2005 by Nuno R. Candeias ORCID, Pedro M. P. Gois ORCID, Carlos A. M. Afonso
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Water is an efficient solvent for the Rh2(OAc)4 catalysed intramolecular C-H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.