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Royal Society of Chemistry, Chemical Communications, 47(50), p. 6214-6216

DOI: 10.1039/c4cc01073f

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The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2

Journal article published in 2014 by Laura Ascherl, Andreas Nordheider, Kasun S. Athukorala Arachchige, David B. Cordes, Konstantin Karaghiosoff, Michael Bühl, Alexandra M. Z. Slawin ORCID, J. Derek Woollins
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Woollins' reagent (, (PhPSe2)2) plays an essential role in the selenation of organic compounds. Reaction of with pyridine gives the P(V) species PhPSe2 stabilised by pyridine coordination which is the first crystallographically characterised mononuclear RPSe2 system stabilised by an external molecule and has potential as a selenation reagent for reactions under mild conditions.