Published in

Royal Society of Chemistry, Dalton Transactions, 33(42), p. 11976

DOI: 10.1039/c3dt51177d

Links

Tools

Export citation

Search in Google Scholar

A half-sandwich 1,2-azaborolyl ruthenium complex: Synthesis, characterization, and evaluation of its catalytic activities

Journal article published in 2013 by Zicheng Liu, Junjie Xu, Wenqing Ruan, Chen Fu, Hui-Jun Zhang ORCID, Ting Bin Wen, Ting-Bin Wen ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

A half-sandwich 1,2-azaborolyl (Ab) ruthenium complex, (Ab-C[triple bond, length as m-dash]CPh)RuCl(PPh3)2 (), has been synthesized by treating RuCl2(PPh3)3 with lithium 1,2-azaborolide L-1, or by treating either RuCl2(PPh3)3 or RuHCl(PPh3)3 directly with 1,2-azaborole LH-1. It is evaluated as a suitable precatalyst in [2 + 2] cycloadditions of norbornene derivatives with DMAD and in atom transfer radical additions of halogenated compounds with olefins.