Published in
Royal Society of Chemistry, Chemical Communications, 5, p. 558-560
DOI: 10.1039/b513624e
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On the role of alkylcobalamins in the vitamin B12-catalyzed reductive dehalogenation of perchloroethylene and trichloroethylene
Journal article published in 2006 by
Derek A. Pratt,
Wilfred A. van der Donk 
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Abstract
Theoretical studies are presented on the structures and reactivity of chlorinated ethylcobalamins, potential intermediates in the vitamin B12-catalyzed reductive dehalogenation of the environmental pollutants perchloroethylene and trichloroethylene; the results suggest an alternative mechanism of catalysis.