Published in
Royal Society of Chemistry, Chemical Communications, 18(51), p. 3762-3765, 2015
DOI: 10.1039/c5cc00236b
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Hydrophobic Monofunctionalized Cucurbit[7]uril Undergoes Self-Inclusion Complexation and Forms Vesicle-Type Assemblies
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Abstract
Hydrophobic monofunctionalized cucurbit[7]uril derivatives (1 and 2) were synthesized by clicking CB[7]-azide with propargylated alkylamines. Compounds 1 and 2 form self-inclusion complexes that are transformed into vesicle-type assemblies by addition of guests (3 – 5) as confirmed by 1H and DOSY NMR, SEM, TEM, and fluorescence spectroscopy.