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Royal Society of Chemistry, Chemical Communications, 40(50), p. 5316-5318, 2014

DOI: 10.1039/c3cc47542e

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A porous metal–metalloporphyrin framework featuring high-density active sites for chemical fixation of CO2under ambient conditions

Journal article published in 2014 by Wen-Yang Gao, Lukasz Wojtas, Shengqian Ma ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Self-assembly of the custom-designed octatopic porphyrin ligand of tetrakis(3,5-dicarboxybiphenyl)porphine with the in situ generated Cu2(CO2)4 paddlewheel moieties afforded a porous metal-metalloporphyrin framework, MMPF-9, which features a high density of Cu(ii) sites confined within nanoscopic channels and demonstrates excellent performances as a heterogeneous Lewis-acid catalyst for chemical fixation of CO2 to form carbonates at room temperature under 1 atm pressure.