Published in

Royal Society of Chemistry, CrystEngComm, 22(17), p. 4070-4074

DOI: 10.1039/c5ce00618j

Links

Tools

Export citation

Search in Google Scholar

Green synthesis of zirconium-MOFs

Journal article published in 2015 by Helge Reinsch, Bart Bueken, Frederik Vermoortele, Ivo Stassen ORCID, Alexandra Lieb, Karl-Petter Lillerud, Dirk De Vos
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction with sulfate anions apparently induces an unusual eightfold connectivity of the Zr cluster.