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Royal Society of Chemistry, Chemical Communications, 7(50), p. 799-801, 2014

DOI: 10.1039/c3cc46336b

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Unveiling the electronic origin of anion order in CrO2−xFx

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Electron-diffraction and high-resolution lattice images reveal superstructure stripes with wave vectors of (1/3, 0, 1/3) and (-1/3, 0, 1/3), which are associated with the ordered arrangement of F(-). Charge density distribution suggests that these stripes manifest themselves electronically as F(-)-Cr(3+)-F(-) zigzag chains, driven by the anisotropic charge interaction of F(-) anions.