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Royal Society of Chemistry, Chemical Communications, 13(50), p. 1555
DOI: 10.1039/c3cc47399f
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Sequential formation of N-doped nanohelicenes, nanographenes and nanodomes by surface-assisted chemical (cyclo)dehydrogenation of heteroaromatics
Journal article published in 2014 by
Anna Lisa Pinardi,
José Ignacio Martínez 
,
Andrej Jančařík,
Irena G. Stará,
Ivo Starý,
María Francisca López,
Javier Méndez,
José Ángel Martín-Gago
,
Andrej Jančařík,
Irena G. Stará,
Ivo Starý,
María Francisca López,
Javier Méndez,
José Ángel Martín-Gago
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Abstract
We report on the stepwise formation of N-doped nanohelicene, nanographene, nanodome and graphene from the same heteroaromatic precursor through subsequent dehydrogenations on Pt(111) upon thermal annealing. The combined experimental (UHV-STM) and computational (DFT) studies attain a full atomistic description of the intermediate reaction stages.